Hugh,
You might want to check out this slideshow from Yahoo News. The photos are beautiful and each library deserves a visit. One of the photos is the replacement to the Library of Alexandria sacked and burned back in the (really) old days.
The Library of Alexandria would be my suggestion for the greatest archive of all time. While both (old and new) are called a library, I think both qualify as a archives. The old library contained information on the (then) ancient world of lost societies and civilizations which surely meets the definition of an archives. The good news is that much of its contents were saved, albeit, looted and relocated to other parts of the world. Secret rooms that survived the fire were found as recently as the 1970's and their contents made available to scholars. The description of the new library (below) says enough on why is it an archive instead of just a library.
http://homes.yahoo.com/photos/10-of-the-world-s-most-spectacular-libraries-1382735436-slideshow/
"BIBLIOTHECA ALEXANDRINA - The original Library of Alexandria, established in the third century B.C., was one of the ancient world's most important centers of knowledge until it was destroyed in the third century A.D. The new Bibliotheca Alexandrina, completed in 2002, was built in hopes of creating a similar destination for scholarship. (snip) The enormous lopsided building, which tilts toward the Mediterranean Sea, holds a range of specialized libraries, four museums, a planetarium, a virtual-reality environment, academic research centers, art galleries, and a conference center." Reference: Yahoo.com
Sherry A Lyons, CRM
The University of Texas Health Science at Houston
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